Modeling relationship between organic carbon partition coefficient and pesticides solubility of pesticides used along the shore of lake Naivasha, Kenya

Citation:

Njoroge, S.M., Munyao, T.M. & Osano, O., 2016. Modeling relationship between organic carbon partition coefficient and pesticides solubility of pesticides used along the shore of lake Naivasha, Kenya. American Journal of Environmental Engineering, 6(2), p.33–37.

Abstract:

Pesticides have many different properties that affect their behaviour in the environment. Pesticide’s solubility
in water has a great impact on leaching potential and environmental fate. The objective of this study was to determine the
relationship between organic carbon based partition coefficient (koc) and pesticides solubility (S) of pesticides used along the
shore of Lake Naivasha using regression analysis. The properties (S, and soil/water equilibrium partition coefficient (kd)) of
pesticides selected from an inventory of pesticides used in farms around Lake Naivasha, were determined from the
manufacturers’ materials safety data sheets. The organic carbon (foc) of the soil from the study area was then determined using
the loss-on-ignition (LOI) method and used to calculate koc. The results showed that the soils around Lake Naivasha had a
mean organic carbon (foc) content of 1.770% and a regression equation for koc and S for the area to be log koc = -0.368logS +
3.256. It was concluded that this relationship can be used to estimate the organic carbon based partition coefficient (koc) of a
pesticide where S is available, and the results compared with values determined experimentally and from other models.

DOI: 10.5923/j.ajee.20160602.01

Recent Publications

Musotsi, P.Y., Otieno, C.A. & Njoroge, S.M., 2017. Prevalence of Fasciolosis in Cattle, Sheep, and Goats Slaughtered in Slaughter Slabs in Trans-Nzoia West, Kenya. and Knowledge of Livestock Handlers. Journal of Biology, Agriculture and Healthcare, 7(6), p.34-43. Abstract

Background: Fasciolosis is known globally to be an important helminthic disease of ruminants caused by liver
fluke species of the genus Fasciola, and it is one of the most neglected tropical zoonotic diseases that can lead to
human infection. It has the widest geographic spread of any emerging zoonotic disease, and it occurs in many
countries of the world. Objectives: The study aimed at determining the prevalence of fasciolosis in ruminants
slaughtered in Trans-Nzoia West. Specific objectives were to establish the trend of fasciolosis in ruminants,
ascertain the relationship between fasciolosis prevalence and rainfall patterns and assess the knowledge of meat
sellers and farmers about fasciolosis. Methodology: A 5-year secondary data retrospective study was carried out
in Trans-Nzoia West, Trans-Nzoia County. The study population consisted of ruminants slaughtered, meat
sellers and livestock farmers.Results: A total of 104,221 cattle, sheep and goats were slaughtered in the five-year
period in which 6,098 (5.85%) were infested with fasciolosis with a prevalence of 6.52%, 6.08% and 4.1 0% in
cattle, sheep, and goats respectively. Most meat sellers (72.2%) were able to identify fasciolosis in infested livers,
88.9% reported liver flukes infestation resulted in the loss of income while 58.3% were not aware of nutrition
depletion associated with fasciolosis. Of the farmers interviewed, 52.9% grazed in swampy areas, 66.7%
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fasciolosis was a zoonotic disease.Conclusion: Fasciolosis was prevalent in the area and caused great economic
loss to the meat sellers. Most farmers were not aware of its cause and zoonotic nature. Recommendations:
Fasciolosis control should be approached from a multidisciplinary angle and farmers should be educated on it
and its zoonotic nature.

Mamboleo, D.M., et al., 2016. The Prevalence of Diarrheal Diseases in Childcare Institutions, Uasin Gishu County, Kenya. International Journal of Research in Environmental Science (IJRES), 2(6), p.5-11. Website Abstract

Diarrheal disease is one of the leading middle income countries. This study examined diarrheal
diseases among children in Uasin Gishu County’s childcare institutions per age, sex, duration of a child in a
childcare institution, and use of soap in hand washing after visiting the toilet. The study involved 202 children
between ages 6 to 20 years old. There were65.8% boy child and 34.2 girls, 71.3% of these children were
between 6-15 years old. The study found 64.4% children used soap to wash hands after toilet. Use of soap in
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Njoroge, S.M., Osano, O. & Munyao, T.M., 2015. Modelling Relationship between Soil Permeability and Organic Carbon in Pesticide Transport into Groundwater. International Journal of Civil and Environmental Engineering, 37(2), p.1423-1427. Abstract

Groundwater contamination by pesticides is an
environmental health concern throughout the world. Many
pesticides do not leach because they are adsorbed on the
soil particles or organic matter even though they may have
a relatively high solubility. The objective of this study was
to determine the relationship between soil permeability
and organic carbon in the transport of pesticides into
groundwater along the shore of Lake Naivasha, using
regression analysis of soil permeability and organic carbon
data collected along the shore. The results showed that the
soil organic carbon (foc) positively affected the soil
permeability (k) and were related by the equation k=
80.724(1.726)foc. It was concluded that organic carbon
increased soil permeability by 30%, thereby recharging the
aquifer while at the same time reducing pesticide transport
into groundwater. Based on these findings the study
recommended that the use of compost (organic
amendments) should be increased in place of inorganic
fertilizers.

Simon M. Njoroge

Senior Lecturer

Modeling relationship between organic carbon partition coefficient and pesticides solubility of pesticides used along the shore of lake Naivasha, Kenya

Citation:

Abstract:

Recent Publications

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