In this work, ZnO thin films were investigated to sense NO2, a gas exhausted by the most common combustion systems polluting the environment. To this end, ZnO thin films were grown by RF sputtering on properly designed and patterned substrates to allow the measurement of the electrical response of the material when exposed to different concentrations of the gas. X-ray diffraction was carried out to correlate the material’s electrical response to the morphological and microstructural features of the sensing materials. Electrical conductivity measurements showed that the transducer fabricated in this work exhibits the optimal performance when heated at 200 °C, and the detection of 0.1 ppm concentration of NO2 was possible. Ab initio modeling allowed the understanding of the sensing mechanism driven by the competitive adsorption of NO2 and atmospheric oxygen mediated by heat. The combined theoretical and experimental study here reported provides insights into the sensing mechanism which will aid the optimization of ZnO transducer design for the quantitative measurement of NO2 exhausted by combustion systems which will be used, ultimately, for the optimized adjustment of combustion resulting into a reduced pollutants and greenhouse gases emission.
Publications
NO2 Gas Sensing Mechanism of ZnO Thin-Film Transducers: Physical Experiment and Theoretical Correlation Study. ACS Sensors. 2016;1(4):406-412.Abstract
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Outsourcing information communication technology services in selected public university libraries in Kenya. Inkanyiso: Journal of Humanities and Social Sciences. 2016;8:44–56.
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Paper in Journal Rehabilitation and Management of Young Girls Commercial Sex Workers: A Case study of Kipsongo Slums in Kitale Town. Kenya sent to Valley International Journals. 2016.
Parameter Identification of a Motor-Gear-Alternator (MGA) System via Step Response Methodology. American Journal of Applied Mathematics. 2016;4:252-257.
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Perioperative Complications Of Radical Hysterectomy At Moi Teaching And Referral Hospital, A Low Resource Setting-A 5 Year R.. International Journal of Gynaecological Cancer . 2016;26:344-344.
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Population density of elephants and other key large herbivores in the Amboseli ecosystem of Kenya in relation to droughts. Journal of Arid Environments. 2016;135:64–74.
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Population Status and Trend of the Maasai Ostrich in the Mid Kenya—Tanzania Borderland. Natural Resources. 2016;7:558.
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Post-LEEP Surveillance in HIV-Positive and HIV-Negative Women in Western Kenya. In: 16Th Biennial Meeting of the International Gynecologic Cancer Society (IGCS). Lisbon, Portugal; 2016. p. Abstract Number IGCS-1011.
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{Post-traumatic stress disorder associated with natural and human-made disasters in the World Mental Health Surveys}. Psychological Medicine. 2016.Abstract
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Poverty Reduction and Economic Growth through Tourism and Travel. In: ATLAS Conference. 2016th ed. Moi University chapter; 2016. p. .
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‘Pregnancy Has Its Advantages’: The Voices of Street Connected Children and Youth in Eldoret, Kenya. PLOS ONE [Internet]. 2016;11:1-17. WebsiteAbstract
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Prevalence and Anti-Microbial Susceptibility of Methicillin Resistant Staphylococcus aureus at Moi Teaching and Referral Hospital Eldoret. Open Journal of Medical Microbiology. 2016;6:9–16.
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The Prevalence of Diarrheal Diseases in Childcare Institutions, Uasin Gishu County, Kenya. International Journal of Research in Environmental Science (IJRES) [Internet]. 2016;2(6):5-11. WebsiteAbstract
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Prevalence of human elephant conflicts in Amboseli ecosystem, Kenya: Current opinions of local community. International Journal of Biodiversity and Conservation. 2016;8:60–71.
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Provision of Education to the ‘Hard to Reach’Amidst Discontinuity in Nomadic Communities in Kenya. In: FIRE: Forum for International Research in Education. Vol. 3. ; 2016. p. 2.
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Provision of Education to the Hard to reach Amidst Discontinuity in Normadic Communities in Kenya. Forum for International Research in Education. 2016;3.
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Q fever, scrub typhus, and rickettsial diseases in children, Kenya, 2011–2012. Emerging infectious diseases. 2016;22:883.
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Quality of life of parents of children with food allergies: mealtimes a treat or threat. International Journal of Current Research. 2016;8:pp–27523.
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Recreation Use Assessment Report. Clemson, SC: Clemson University; 2016 p. .
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